By Erzsébet Néher-Neumann
Advanced Potentiometry presents a platform for the actual interpretation of potentiometric titration info. It adequately offers the calculation of balance constants and equilibrium procedures with no systematic error. This authoritative monograph info the calculation of the entire capability anomalies/systematic error in emf cells containing both combos of sturdy electrolytes or equilibrium structures in any respect the experimental stipulations mostly utilized in potetiometric titrations. It additionally provides a severe research of those methods.
The e-book info a style that's right and unfastened from systematic error in addition to one who effectively describes either nature and the surroundings. it's the perfect source for prime tuition lecturers, academics, researchers, PhD graduates and undergraduate scholars operating within the fields of answer chemistry, actual chemistry, inorganic chemistry and analytical chemistry and environmental research.
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Extra info for Advanced Potentiometry: Potentiometric Titrations and Their Systematic Errors
3. N´eher-Neumann E (1997) The liquid junction potential in potentiometric titrations. 1. The calculation of potentials across liquid junctions of the type AY|AY + BYz(B) + HY for cells with mixtures of strong electrolytes. Acta Chem Scand 51: 1141–1154. 4. N´eher-Neumann E (1987) The liquid junction EMF. Dissertation. Royal Institute of Technology (KTH), Stockholm. 5. Benedek P (1954) A kemiai technologiai szamitasok fizikokemiai alapjai. II. Resz, H¨o es munka. pp. 21–29. Tank¨onyvkiado, Budapest.
2) All ions which are present in the test solution contribute as an extra term to the ideal electrode potential of every measuring electrode. For the mixtures studied, it was found that the total potential anomalies in Cells B and H can be given as follows. 61) For the estimation of E0B and E0H , moreover, the calculated slope functions, we need accurate conductivity data, which were determined in exactly the same mixtures what were used in the emf studies, for the determination of E0B and E0H .
2]. The validity of this approximation should be checked by using the ionic molar conductivities determined in the mixtures studied. 5 ≤ C ≤ 3 M. 26) In the potential function EDf and in the term “corr”, the function Φ1 (x) is included. This summarizes the Debye–H¨uckel terms of the activity coefficients. In the present experimental condition, it has the following value. 1. g. the two contributions of the activity factors to the total potential anomalies. For this cell, the potential functions given below are valid.